Sodium chloride written of two ions Na+ and also Cl- is one ionic compound having actually the chemistry formula NaCl. It shows up as a white crystalline solid and also is generally odorless in nature. The most usual use of sodium chloride is in the Solvay process for the production of salt carbonate and also calcium chloride.

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In this article, us will comment on sodium chloride (NaCl) lewis dot structure, crystal or lattice structure, is it polar or nonpolar, shape, unit cell, etc.

Sodium chloride is generally used as a condiment and food preservative, and also in various commercial processes for the manufacturing of assorted chemicals. Also, it has actually a duty as an emetic and a flame retardant.

Properties of sodium chloride

It has a molar fixed of 58.443 g/mol.It shows up as a white crystalline solid.It has a melting allude of 800.7 °C and also a boiling allude of 1,465 °C.Sodium and also chloride ions stand for in 1:1 in NaCl chemical formula.It has a name: coordinates geometry of octahedral because that Na+ and Cl-.
Name that MoleculeSodium chloride
Chemical formulaNaCl
Coordination number6:6
Unit cells4
Crystal structureFace-centered cubic
Total Valence electron for NaCl lewis structure8

Page Contents show
1 exactly how to draw lewis structure for NaCl (Sodium chloride)?
2 measures to draw electron dot framework or lewis dot structure of NaCl
3 What is the decision or lattice structure of NaCl and also its unit cell?
4 sodium chloride polarity: is NaCl polar or nonpolar?
6 an introduction

How to attract lewis structure for NaCl (Sodium chloride)?

NaCl lewis framework is distinctive and very interesting to draw due to the fact that it is an ionic compound created from metal(Na+) and also nonmetal(Cl-). The lewis dot framework of NaCl consists of one hopeful charge on salt metal and one an unfavorable charge on chlorine nonmetal. We have to represent lock by putting brackets approximately them.

The lewis diagram of one ionic link is created with a different strategy than the common procedure we supplied for drawing the compounds like NH3, BF3, BrF5, etc.

Steps to attract electron dot framework or lewis dot framework of NaCl

Step 1: In the an initial step, we have to count the valence electron easily accessible for drawing the lewis framework of NaCl. For discovering the valence electron you need to remember a periodic team of each atom.

As salt belongs to the 1st periodic group and chlorine belongs to the 17th group, hence, the valence electron of salt is 1 and for the chlorine atom, the is 7.

⇒ sodium valence electron = 1

⇒ Chlorine valence electron = 7

∴ complete valence electron obtainable for illustration the lewis dot framework of NaCl = 1 + 7 = 8 valence electrons


Step 2: In ionic compounds, the steel atom is the electron donator and also the nonmetal atom is the electron acceptor. So, in the instance of the NaCl compound, the sodium(Na) is the metal that desires to give the one-electron away and also forms Na+ ion conversely, chlorine is the nonmetal that will certainly accept the one-electron and forms Cl- ion.




As you check out in the over figure, Na metal donated that one electron to the chlorine nonmetal, hence, Na creates Na+ cation and Cl creates Cl- anion.

The lewis diagram is all around completing the octet that atoms and also achieving stability.

For the Na atom to obtain an octet, it must lose an electron; for the Cl atom to get an octet, that must obtain an electron. 

So, in the above NaCl lewis structure, the chlorine ion gets 8 electrons stood for as dots in the outermost shell, hence, completed stability due to the fact that it perfect the octet.

Whereas sodium atom has only one valence electron in that is outermost shell, so providing it increase would an outcome in the very same electron configuration together neon(noble gas).

Hence, both chlorine and sodium ions have the electron configurations of noble gases, v a complete valence shell.

⇒ salt loses the electron, for this reason it profit a hopeful charge.

⇒ The chlorine atom accepts the electron, thus it gains a negative charge.

The positive and negative charge ion of sodium and also chloride will entice each other to creates an ionic bond.


In the NaCl lewis dot structure, we put the bracket roughly sodium and also chlorine atoms to show their positive and an unfavorable charges.

That’s all, we have completed the lewis framework of the NaCl (sodium chloride) compound.


What is the crystal or lattice framework of NaCl and its unit cell?

A crystal framework is merely a three-dimensional arrangement of the atoms in room whereas lattice is a geometrical concept that is provided to describe the structure of the crystal.

“When a group of molecules tends to arrange each unit repetitively at a lattice point, a crystal is made.”

In a decision structure, there is a sample of arranging the atom or units. These patterns are located upon the points of a lattice. These lattice points are arranged in a three dimensionally ordered manner.

Now, what is the lattice or crystal framework of NaCl? NaCl has actually a cubic decision system and face-centered lattice type, this can additionally be said, NaCl has actually a crystalline framework of face-centered cubic.

NaCl is a confront centred cubic unit cell the has four cations and four anions.

“Unit cells are the simplest an easy units i m sorry repeat itself in a details pattern to form a finish crystal lattice.”

The crystal structure of NaCl salient feature:

NaCl has two ions (Na+ and Cl-) basis, “A basis is characterized as the atom or team of atoms the are associated with each lattice suggest in the crystal system.The lattice of sodium chloride has 8 total ions in one unit cell, four are Na+ ions and also the other 4 are Cl- ion.Sodium-ion is current at the body centre and edge-centres when chloride is existing at corners and also face centres. That can additionally be interchanged.Every Na+ ion is surrounding by 6 Cl- ion whereas every Cl- ion is additionally surrounded by 6 Na+ ions. So, we deserve to say NaCl structure has 6:6 coordination because coordination number defines the variety of atoms or ion immediately about a particular atom or ion.

The edge site that the NaCl crystal framework is common by the 8 unit cell (1 corner equal come 1/8 the ion or atom) and also the 6 challenge site is shared by 1/2 atoms or ions.

So, the total number of ions or atoms present in face-centred cubic that NaCl unit cell = 8(1/8) + 6(1/2) = 4

∴ There are 4 atom or ions current in every unit cell of a challenge centred cubic structure, hence, the variety of NaCl units present in a unit cabinet of NaCl is 4


Image source: Google image

NaCl has a cubic unit cell that have the right to be represented as a face-centred cubic range of anions with an interpenetrating fcc cation lattice (or vice-versa). This unit cabinet of NaCl look at the exact same whether we start with cations or anions in ~ the corners. Each of these ion is 6-coordinate and has a regional octahedral geometry.(source)

There is so much confusion because that the students on even if it is NaCl is polar or nonpolar in nature?

As us know, NaCl is one ionic compound made up of one metal and also nonmetal. It contains two ions Na+ and also Cl- that are attracted through the electrostatic pressure generated between them.

If us go with the true definition of polar and nonpolar in chemistry, it is stated that polar molecules have actually some net dipole moment and also it occurs where the large difference the electronegativity in between the atom exists whereas nonpolar molecule is just opposite come it.

In the NaCl compound, Na+ has actually an electronegativity of 0.93, and also chlorine ion has an electronegativity that 3.16, the distinction of electronegativity between them is greater than 2.

As every Pauling scale

⇒ when the electronegativity difference in between the atom is greater than 2, climate the compound is said to it is in ionic in nature.

⇒ when the electronegativity difference in between the atom is much less than 0.5, climate the link is claimed to it is in nonpolar covalent in nature.

⇒ when the electronegativity difference between the atoms lies in between 0.5 come 2, climate the link is stated to it is in polar covalent in nature.

So, in the case of the NaCl compound, the distinction of electronegativity in between atoms is higher than 2, hence, it definitely is one ionic compound.

But Is NaCl polar or nonpolar? NaCl is neither polar no one nonpolar due to the fact that the link formed between the Na+ and Cl- is ionic, the polar and also nonpolar usually take place where the covalent bonds between the atom exist.

Ionic bonds happen when over there is a complete transfer of electron from one atom to another and also they are associated by the electrostatic pressure of attraction conversely, a covalent link is share of electrons in between the atoms.

Even NaCl atoms are separated by hopeful and negative charge, and also the difference of electronegativity in between the Na and Cl is high, still, we can’t say NaCl is polar or nonpolar.

Polar and also nonpolar terms are reserved for molecule compounds favor NCl3, NH3, H2O, etc. – the is not used to the ionic compounds prefer NaCl.

If you ignore the term “covalent character” in compounds, then yes, you deserve to say NaCl is a polar molecule on the communication of the electronegativity difference between Na+ and Cl-.

Also, polar molecules have actually a significant covalent character and an extremely minor ionic character, and also in NaCl compound, it has actually a very big ionic character, so, we can’t speak it is either polar or nonpolar.

So, in the situation of NaCl lewis dot structure, Na atom is metal and Cl is a nonmetal, so, in stimulate to complete the octet and also gains the stability, Na steel transfer one electron come the chlorine atom.

After transferring the electron, the sodium atom gains the confident charge(Na+) whereas the chlorine atom gains the an adverse charge(Cl-).

Both ions(Na+ and Cl-) lie in the zone of noble gas configuration with complete valence shell, hence, gains stability.

Therefore, in order to complete the octet and gain stability, the change of electrons from one steel to nonmetal takes place.

How numerous molecules of NaCl are current in each unit cell?

The edge site the the NaCl crystal framework is shared by the 8 unit cell (1 edge equal to 1/8 of ion or atom) and the 6 challenge site is mutual by 1/2 atoms or ions.

So, the total number of ions or atoms current in face-centred cubic of NaCl unit cabinet = 8(1/8) + 6(1/2) = 4

∴ each unit cell has 4 atoms of every Na+ and also Cl-. Hence, over there is a total the 4 molecule of NaCl in each unit cell.

What space the lattice type and decision systems existing in the NaCl compound?

NaCl has a Face centered lattice kind and cubic crystal system.

Or you can say “The Bravais lattice of NaCl is a face-centered cubic lattice”.

Why is NaCl link neither polar no one nonpolar in nature?

This is since the bond the occurs between the Na+ and Cl+ is ionic, no covalent.

For polar and nonpolar nature, there should be a high covalent personality in molecule and also atoms should be share electrons through a covalent bond.

But in the situation of the NaCl compound, the Na atom transfers the electron fully to the Cl atom, hence, over there is no share of electrons between these like a covalent bond.

Therefore, we can say, the existence of high ionic character in NaCl leads to no polar nor nonpolar in nature.

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The full valence electron is easily accessible for drawing the Sodium chloride (NaCl) lewis structure is 8.NaCl is a face-centered cubic unit cell the has four cations and also four anions.In the NaCl lewis dot structure, the salt atom completes that is octet by delivering one electron to the chlorine atom.NaCl has actually a Face centered lattice form and cubic crystal system.Sodium chloride (NaCl) compound is neither polar no one nonpolar, the is one ionic compound with very high ionic character. If you neglect the term “covalent personality or covalent bond” native the polar or nonpolar definition, climate on the communication of electronegativity difference between Na+ and also Cl-, you can say NaCl is a polar molecule.